2009 01 v.27;No.220 1-6
静电纺丝法制备锂离子电池隔膜的研究进展
基金项目(Foundation):
邮箱(Email):
DOI:
中文作者单位:
华南理工大学材料学院;
摘要(Abstract):
利用静电纺丝技术可以制得高比表面积、高孔隙率的纤维及纤维毡状材料,使其在制备锂离子电池隔膜中具有明显的应用优势。综述了采用静电纺丝法制备纳米纤维膜用作电池隔膜的技术特点及其主要影响因素。重点阐述了静电纺隔膜的结构和性能,如膜的形态结构、机械性能、化学稳定性和热稳定性等。
关键词(KeyWords):
静电纺丝;;电池隔膜;;结构;;性能
| 2,535 | 53 | 49 |
| 下载次数 | 被引频次 | 阅读次数 |
参考文献
[1]任小龙,刘渝洁,冯勇刚,等.电池隔膜制造方法研究进展[J].绝缘材料,2007,40(4):36-38.
[2]GAO Kun,HU Xinguo,DAI Chongsong,et al.Crystalstructures of electrospun PVDF membranes and its sepa-rator application for rechargeable lithium metal cells[J].Materials Science and Engineering,2006,131:100-105.
[3]胡继文,许凯,沈家瑞.锂离子电池隔膜的研究与开发[J].高分子材料科学与工程,2003,19(1):215-219.
[4]MORIGKI K,KABUTO N.Manufacturing method of aseparator for a lithium secondary battery and an organicelectrolyte lithium secondary battery using the sameseparator:US,5 597 659[P].1997-1-28.
[5]任旭梅,吴锋,白莹.倒相法制备多孔PVDF隔膜的探索[J].电化学,2001,7(4):501-505.
[6]PUWeihua,HE Xiangming,WANG Li,et al.Prepara-tion of P(AN-MMA)microporous membrane for Li-ionbatteries by phase inversion[J].Journal of MembraneScience,2006,280:6-9.
[7]任旭梅,吴锋.用PAN作造孔剂制备聚合物锂离子电池隔膜[J].电池,2002,32:36-37.
[8]程琥,杜洪彦,杨勇.新型锂电池用复合隔膜的制备及其电化学性能表征[J].电化学,2003,10(3):303-306.
[9]唐定国,慈云祥,刘丽慧,等.一种新型聚合物锂离子电池的制备和性能研究[J].北京大学学报(自然科学版),2006,42:48-50.
[10]HUANG Zhengming,ZHANG Y Z,KOTAKI M,et al.A review on polymer nanofibers by electrospinning andtheir applications in nanocomposites[J].CompositesScience and Technology,2003,63:2223-2253.
[11]吴大城,杜仲良,高绪珊.纳米纤维[M].北京:化学工业出版社,2001.
[12]SHIN Y M,HOHMAN M M,BRENNER M P,et al.Experimental characterization of electrospinning:theelectrically forced jet and instabilities[J].Polymer,2001,42:9955-9967.
[13]HANTao,ALEXANDER LY,RENEKER D H.Visco-elastic electrospun jets:Initial stresses and elonationalrheometry[J].Polymer,2008,49:1651-1658.
[14]THOMPSON C J,CHASE G G,YARIN A L,et al.Effects of parameters on nanofiber diameter determinedfrom electrospinning model[J].Polymer,2007,48:6913-6922.
[15]RENEKER D H.Structure and morphology of small di-ameter electrospun aramid fiber[J].Polymer,1995,36:195-201.
[16]RENEKER D H,YARIN A L,FONG H,et al.Ben-ding instability of electrically charged liquid jets of poly-mer solutions in electrospinning[J].Journal of AppliedPhysics,2000,87:4531-4547.
[17]SMIT E,BUTTNER U,SANERSON R D.Continuousyarns from electrospun fibers[J].Polymer,2005,46:2419-2423.
[18]DOSHI J,RENEKER D H.Electrospinning process andapplications of electrospun fibers[J].Journal of Elec-trostatics,1995,35:151-160.
[19]王磊,邓岩,徐军,等.高压静电纺丝法制备偏氟乙烯聚合物无纺布的研究[J].哈尔滨理工大学学报,2005,19(3):11-13.
[20]PUWeihua,HE Xiangming,WANG Li,et al.Prepara-tion of PVDF-HFP microporous membrane for Li-ionbatteries by phase inversion[J].Journal of MembraneScience,2006,272:11-14.
[21]CHO TH,TANAKAM,ONISHI H,et al.Battery per-formances and thermal stability of polyacrylonitrile nano-fiber-based nonwoven separators for Li-ion battery[J].Journal of Power Sources,2008,181:155-160.
[22]ZHANG S S,ERVIN M H,Xu K,et al.Microporouspoly(acrylonitrile-methyl methacrylate)membrane as aseparator of rechargeable lithium battery[J].Electro-chimica Acta,2004,49:3339-3345.
[23]崔闻宇.聚合物锂离子电池隔膜的研究[D].哈尔滨:哈尔滨工业大学,2006.
[24]ZHANG Shengshui.A reviewon the separators of liquidelectrolyte Li-ion batteries[J].Journal of PowerSources,2007,164:351-364.
[25]CHERUVALLY G,KIM J K,CHOI J W,et al.Elec-trospun polymer membrane activated with room tempera-ture ionic liquid:Novel polymer electrolytes for lithiumbatteries[J].Journal of Power Sources,2007,172:863-869.
[26]BANSAL D,MEYER B,SALOMON M.Gelled mem-branes for Li and Li-ion batteries prepared by electro-spinning[J].Journal of Power Sources,2008,178:848-851.
[27]KIM J R,CHOI S W,JO S M,at el.ElectrospunPVdF-based fibrous polymer electrolytes for lithium ionpolymer batteries[J].Electrochimica Acta,2004,50:69-75.
[28]ABRAHAM K M,ALAMGIR M.Polymer electrolytesreinforced by Celgard(r)membranes[J].Journal of theElectrochemical society,1995,142(3):683-687.
[29]赵治贞.电纺制备聚偏氟乙烯超细纤维膜及性能研究[D].天津:天津大学,2004.
[30]CHOI S S,LEE Y S,JOO C W,et al.ElectrospunPVDF nanofiber web as polymer electrolyte or separator[J].Electrochimica Acta,2004,50:339-343.
[31]赵亮.PVDF-HFP超细纤维膜及其以PEGDMAC交联改性研究[D].天津:天津大学,2006.
[32]吴大勇,刘昌炎.锂离子电池隔膜研究及国产化进展[J].新材料产业,2006,8:48-53.
[2]GAO Kun,HU Xinguo,DAI Chongsong,et al.Crystalstructures of electrospun PVDF membranes and its sepa-rator application for rechargeable lithium metal cells[J].Materials Science and Engineering,2006,131:100-105.
[3]胡继文,许凯,沈家瑞.锂离子电池隔膜的研究与开发[J].高分子材料科学与工程,2003,19(1):215-219.
[4]MORIGKI K,KABUTO N.Manufacturing method of aseparator for a lithium secondary battery and an organicelectrolyte lithium secondary battery using the sameseparator:US,5 597 659[P].1997-1-28.
[5]任旭梅,吴锋,白莹.倒相法制备多孔PVDF隔膜的探索[J].电化学,2001,7(4):501-505.
[6]PUWeihua,HE Xiangming,WANG Li,et al.Prepara-tion of P(AN-MMA)microporous membrane for Li-ionbatteries by phase inversion[J].Journal of MembraneScience,2006,280:6-9.
[7]任旭梅,吴锋.用PAN作造孔剂制备聚合物锂离子电池隔膜[J].电池,2002,32:36-37.
[8]程琥,杜洪彦,杨勇.新型锂电池用复合隔膜的制备及其电化学性能表征[J].电化学,2003,10(3):303-306.
[9]唐定国,慈云祥,刘丽慧,等.一种新型聚合物锂离子电池的制备和性能研究[J].北京大学学报(自然科学版),2006,42:48-50.
[10]HUANG Zhengming,ZHANG Y Z,KOTAKI M,et al.A review on polymer nanofibers by electrospinning andtheir applications in nanocomposites[J].CompositesScience and Technology,2003,63:2223-2253.
[11]吴大城,杜仲良,高绪珊.纳米纤维[M].北京:化学工业出版社,2001.
[12]SHIN Y M,HOHMAN M M,BRENNER M P,et al.Experimental characterization of electrospinning:theelectrically forced jet and instabilities[J].Polymer,2001,42:9955-9967.
[13]HANTao,ALEXANDER LY,RENEKER D H.Visco-elastic electrospun jets:Initial stresses and elonationalrheometry[J].Polymer,2008,49:1651-1658.
[14]THOMPSON C J,CHASE G G,YARIN A L,et al.Effects of parameters on nanofiber diameter determinedfrom electrospinning model[J].Polymer,2007,48:6913-6922.
[15]RENEKER D H.Structure and morphology of small di-ameter electrospun aramid fiber[J].Polymer,1995,36:195-201.
[16]RENEKER D H,YARIN A L,FONG H,et al.Ben-ding instability of electrically charged liquid jets of poly-mer solutions in electrospinning[J].Journal of AppliedPhysics,2000,87:4531-4547.
[17]SMIT E,BUTTNER U,SANERSON R D.Continuousyarns from electrospun fibers[J].Polymer,2005,46:2419-2423.
[18]DOSHI J,RENEKER D H.Electrospinning process andapplications of electrospun fibers[J].Journal of Elec-trostatics,1995,35:151-160.
[19]王磊,邓岩,徐军,等.高压静电纺丝法制备偏氟乙烯聚合物无纺布的研究[J].哈尔滨理工大学学报,2005,19(3):11-13.
[20]PUWeihua,HE Xiangming,WANG Li,et al.Prepara-tion of PVDF-HFP microporous membrane for Li-ionbatteries by phase inversion[J].Journal of MembraneScience,2006,272:11-14.
[21]CHO TH,TANAKAM,ONISHI H,et al.Battery per-formances and thermal stability of polyacrylonitrile nano-fiber-based nonwoven separators for Li-ion battery[J].Journal of Power Sources,2008,181:155-160.
[22]ZHANG S S,ERVIN M H,Xu K,et al.Microporouspoly(acrylonitrile-methyl methacrylate)membrane as aseparator of rechargeable lithium battery[J].Electro-chimica Acta,2004,49:3339-3345.
[23]崔闻宇.聚合物锂离子电池隔膜的研究[D].哈尔滨:哈尔滨工业大学,2006.
[24]ZHANG Shengshui.A reviewon the separators of liquidelectrolyte Li-ion batteries[J].Journal of PowerSources,2007,164:351-364.
[25]CHERUVALLY G,KIM J K,CHOI J W,et al.Elec-trospun polymer membrane activated with room tempera-ture ionic liquid:Novel polymer electrolytes for lithiumbatteries[J].Journal of Power Sources,2007,172:863-869.
[26]BANSAL D,MEYER B,SALOMON M.Gelled mem-branes for Li and Li-ion batteries prepared by electro-spinning[J].Journal of Power Sources,2008,178:848-851.
[27]KIM J R,CHOI S W,JO S M,at el.ElectrospunPVdF-based fibrous polymer electrolytes for lithium ionpolymer batteries[J].Electrochimica Acta,2004,50:69-75.
[28]ABRAHAM K M,ALAMGIR M.Polymer electrolytesreinforced by Celgard(r)membranes[J].Journal of theElectrochemical society,1995,142(3):683-687.
[29]赵治贞.电纺制备聚偏氟乙烯超细纤维膜及性能研究[D].天津:天津大学,2004.
[30]CHOI S S,LEE Y S,JOO C W,et al.ElectrospunPVDF nanofiber web as polymer electrolyte or separator[J].Electrochimica Acta,2004,50:339-343.
[31]赵亮.PVDF-HFP超细纤维膜及其以PEGDMAC交联改性研究[D].天津:天津大学,2006.
[32]吴大勇,刘昌炎.锂离子电池隔膜研究及国产化进展[J].新材料产业,2006,8:48-53.
基本信息:
DOI：
中图分类号:TM912
引用信息:
[1]张传文,严玉蓉,区炜锋等.静电纺丝法制备锂离子电池隔膜的研究进展[J].产业用纺织品,2009,27(01):1-6.
基金信息: