| 7,927 | 183 | 73 |
| 下载次数 | 被引频次 | 阅读次数 |
静电纺丝是目前唯一能够直接、连续制备聚合物纳米纤维的方法。概述了静电纺丝技术及其发展历程,静电纺丝射流的稳态和非稳态的研究成果。介绍了静电纺丝机、静电纺丝技术的新进展及静电纺纳米纤维膜的应用。最后指出静电纺丝的研究方向。
Abstract：Electrospinning is the only way to produce polymer nanofibers directly and continuously at present.The technology and historical development of electrospinning were summarized in this paper.The jet′s stability and instability states of electrospinning were discussed.The electrospinning machines,new development of electrospinning and the applications of nanofiber membranes were introduced.The research direction of electrospinning was indicated.
[1]FORMHALS A.Process and apparatus for preparing ar-tificial threads:US,1,975,504[P].1934.
[2]SIMONS HL.Process and apparatus for producing pat-terned non-woven fabrics:US,3,280,229[P].1966.
[3]LARRONDO L,JOHN R S T.Electrostatic fiber spin-ning from polymer melts[J].J Polym Sci Polym Phys,1981,19:909.
[4]DOSHI J,RENEKER D H.Electrospinning process andapplications of electrospun fibers[J].Electrostat,1995,35:151.
[5]FONG H,CHUN I,RENEKER D H.Beaded nanofi-bers formed during electrospinng[J].Polymer,1999,40:4585.
[6]BUCHKO C,CHEN L C,SHEN Y,et al.Processingand microstructural characterization of porous biocom-patible protein polymer thin films[J].Polymer,1999,40:7397.
[7]SPIVAK AF,DZENIS Y A,RENEKER D H.Amodelof steady state jet in the electrospinning process[J].Mech Res Com,2000,27:37.
[8]RENEKER D H.Bending instability of electricallycharged liquid jets of polymer solutions in electrospin-ning[J].Appl Phys,2000,87(9):4531.
[9]覃小红,王新威,胡祖明,等.静电纺丝聚丙烯睛纳米纤维工艺参数与纤维直径关系的研究[J].东华大学学报,2005,31(6):16-21.
[10]PAN H,LI L M,HUL,et al.Continuous aligned pol-ymer fibers produced by a modified electrospinningmethod[J].Polymer,2006,47(14):4901-4904.
[11]吴大诚.纳米纤维[M].北京:化学工业出版社,2003:44.
[12]SPIVAK AF,DZENIS Y A.Asymptotic decay of radiusof a weakly conductive viscous Jet in an external electricfield[J].Appl Phys Lett,1998,73(21):3067-3069.
[13]QIN X H,WANG Y Q,HE J H,et al.Effect of LiClon electrospinning of PAN polymer solution:theoreticalanalysis and experimental verification[J].Polymer,2004,45:6409-6413.
[14]QIN X H,WANG S Y,SANDRA T,et al.Effect ofLiCl on the stability length of electrospinning jet by PANpolymer solution materials[J].Polymer,2005,59:3102-3105.
[15]YU J H,FRIDRIKH S V,RUTLEDGE G C.The roleof elasticity in the formation of electrospun fibers[J].Polymer,2006,47(13):4789-4797.
[16]SHAO C L,GUAN HY,LIUY C,et al.MgO nanofi-bres via an electrospinning technique[J].Journal ofMaterial Science,2006,41(12):3821-3824.
[17]ZHANG Y Z,VENUGOPAL J,HUANG Z M,et al.Crosslinking of the electrospun gelatin nanofiber[J].Polymer,2006,47(8):2911-2917.
[18]WONG K K H,ZINKE-ALLMANG M,Wan W K.N+surface doping on nanoscale polymer fabrics via ion im-plantation[J].Nuclear Instruments&Methods in Phy-sics Research Section B-beam Interactions with Materialsand Atoms,2006,249:362-365.
[19]MA Z W,RAMAKRISHNA S.Ce(IV)-induced graftcopolymerization of methacrylic acid on electrospunpolysulphone nonwoven fiber membrane[J].Journal ofApplied Polymer Science,2006,101(6):3835-3841.
[20]YANG G C,GONG H,YANG R,et al.Modification ofelectrode surface through electrospinning followed byself-assembly multilayer film of polyoxometalate and itsphotochromic[J].Electrochemistry Communications,2006,8(5):790-796.
[21]YOON K,KIM K,WANG X F,et al.High flux ultra-filtration membranes based on electrospun nanofibrousPAN scaffolds and chitosan coating[J].Polymer,2006,47(7):2434-2441.
[22]PEDICINI A,FARRIS R J.Thermally induced colorchange in electrospun fiber mats[J].J Polym SciPolym Phys,2004,42:752.
[23]DING B,YAMAZAKI M,SHIRATORI S.Electrospunfibrous polyacrylic acid membrane-based gas sensors[J].Sensors and Actuators,2005,106:477-483.
[24]ZHU Y,ZHANG J C,ZHENG Y M,et al.Stable,su-perhydrophobic,and conductive polyaniline/polystyrenefilms for corrosive environments[J].Advaned FuctionalMaterials,2006,16:568-574.
[25]PAN C,GU Z Z,NAGAI K,et al.SnO2target withcontrollable microstructure and thickness for generatingextreme ultravioletlight[J].Journal of Applied Phy-sics,2006,100(1):3.
基本信息:
DOI：
中图分类号:TQ340.6
引用信息:
[1]杨恩龙,王善元,李妮等.静电纺丝技术及其研究进展[J].产业用纺织品,2007,No.203(08):7-10+14.
基金信息:
国家自然科学基金资助项目(10602014)